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Organic Chemistry Bonding

Reduction of Carvone

In the reduction of a carvone can you effectively form an isomer when C=O is reduced?

Identifying Organic Compounds

A colorless liquid A (C3H6O) was soluble in water and ether, and had a boiling point of 94-96 degrees Celsius. It decolorized a Br2-CH2Cl2 solution and gave a positive ceric nitrate test. On catalytic hydrogenation it formed Compound B (C3H8O), which did not decolorized the above bromine solution, but did give a positive ceric n

Determining Molecules from Spectral Diagrams

Compound S (C8H16) decolorizes a solution of bromine in carbon tetrachloride. The broadband proton-decoupled 13^C spectrum of S is given in Fig. 9.52. Propose a structure for S. I have attached the actual question from the book as it has Fig. 9.52 in it. There was minor blurring near the end of the chart so just for refere

Assorted State Change Questions

1 Describe the intermolecular force that must be overcome in converting each of the following from a liquid to a gas: A. Liquid O2 B. Mercury C. CH3I (methyl iodide) D. CH3CH2OH (ethanol) 2 Rank the following in order of increasing strength of intermolecular forces in the pure substances. Which do you think

Ceric Nitrate, Beyer, and Tollens Tests

I need some help in finding out what the compounds are from the scenarios: 1. A colorless liquid A (C3H6O) was soluble in water and ether, and had a boiling point of 94-96 degrees C. it decolorized a Br2-CH2Cl2 solution and gave a positive ceric nitrate test. On catalytic hydrogenation it formed Compound B (C3H8O), which

Chemical Differences Among Carbohydrates

1) How can you distinguish chemically between starch and three other carbohydrates (sucrose, glucose, & lactose)? 2) What would you expect to observe when adding one drop of iodine-potassium iodine reagent to each of the four carbohydrates? 3) How does Benedict's Reagent distinguish between carbohydrates? 4) When addi

Which of the following is an INCORRECT description of benzene?

Which of the following is an INCORRECT description of benzene? a. The CCC bond angles are all equal to 120 o b. The 6-membered ring contains alternating double and single carbon-carbon bonds c. The molecule may be drawn as resonance hybrid of 2 Kekule structures d. The molecule is planar Which of the followi

Chemical structures, hydrocarbons, and solubility

What is the structure for hexadecanol? What would explain why it is a solid rather than a liquid? How are ethanol, 1-octanol, propane-1,2,3-triol, and hexadecanol similar to their corresponding hydrocarbons (ethane, octane, propane, & hexadecane)? Do some of these alcohols possess more hydrocarbon character than other

Organic Oxygen Compounds

Can an ether molecule be made out of a methanol or ethanol molecule? Why or why not? What is the structure for 1-Octanol & Propane-1,2,3-triol? How would Ethanol, 1-Octanol, & Propane-1,2,3-triol compare in viscosity (ability to flow)? Why? Do their size, shape, or molecular structure affect their physical consistency

Organic Chemistry

(See attached file for full problem description) 5. Propose a mechanism to account for the following conversion of testoterone to the alkene shown 6 Two compounds (A and B) have formulas C3H8O. They gave the following results with three chemical tests. Propose structures for A and B consistent with this informaion. 7. A

Naming Compounds

Is the following the correct structural formula for trans-3,4-dimethyl-3-hexene? CH3 CH3 | / CH3-CH-C=C | CH3 C2H5

Aromatic structures, and mass spec, molecular ion, realtive abundances

1.(refering to dexchlorpheniramine, pilocarpine, and 9-aminoacridine)--GO TO WWW.CHEMFINDER.COM TO LOOK UP STRUCTURES FOR THESE COMPOUNDS)-- For each ring in each structure, indicate if it is aromatic. Rationalize your decision for each ring (even those that are not aromatic). Make sure to indicate which (if any) lone pair el

Organic chemistry problems: Naming, Isomerism, pH

IUPAC name for CH3CH2CH2CH double bond CHCH2COOH Which exhibits geometric isomerism CH3C triple bond CH CH3CH2CH double bondCH2 CH3CH double bond CHCH3 Compound A has the molecular formula C8H14. Addition of bromine to A gives a new compound B, with the formula C8H14Br4. Treatment of A with and aqueous acid gave

Naming an IUPAC system

Name this by the IUPAC system H H / C=C / C-C C-C-C | Cl And this one: C-C-C-C-C | | F C-F

Stepwise mechanisms

Consider the reaction in attached document. What is a stepwise mechanism that accounts for both of the products shown. Please show me the mechanism. Show all intermediate structures and all electron flow with arrows. Also include resonance. In addition, what are the non-prefered products of electrophilic addition to the opposit

Acid catalyzed Fisher

Propose a detailed mechanism for the acid - catalyzed Fisher esterification of propanoic acid and ethanol. Show all resonance forms.

two structures

Please see attached...I chose c The two structures shown are: a. constitutional isomers b. enantiomers c. different resonance forms of the same species. d. difference conformations of the same species. e. 5. diastereomers

Organic Chemistry Bonding Properties

I need some help with these three questions on organic chemistry bonding: 13. Why it is important that any aldehyde used in Witting reaction be free of carboxylic acid impurities? 14. Explain why the C=C stretching mode gives rise to a rather weak IR band in 1-methylcyclohexane, while in its isomer, methylenecyclohexene,

What is the structure of the hydrocarbon?

A hydrocarbon was found to have a molecular weight of 80-85. A 10.02 mg sample took up 8.40 mL of H2 gas at 0 degrees C and 760 mm pressure. Ozonolysis yielded only two compounds shown in the attached .jpg. What is the structure of the hydrocarbon? See attached file for full problem description.

Calculate the degree of unsaturation in C4H6.

1. a. Calculate the degree of unsaturation in C4H6. b. Draw at least 4 iosmers with this formula (C4H6). 2. a. Explain why cis dichloroethene has a boiling point of 60 degrees C while trans - dichloroethen has a boiling point of 48 degrees C. b. Include drawings of the structures with dipoles in your answer.

Anti Addition

I need to paraphrase this "As a bromine molecule approaches perpendicular to the negatively charged pi cloud of the carbon-carbon double bond, its bonding electrons are repelled away from the bromine atom nearer the double bond, leaving it with a partial positive charge. As the positively charged bromine penetrates the pi cloud,

Isomers of dimethylcyclohexanediol

Here is my question. I am working through this and some other problems, and want to compare what I do against what someone who knows a lot more than me on this subject, does. Please don't do this problem if you are 1. Planning on copying and pasting something from a website (yes, I've had people do that to me here) that

Organic Chemistry Structure and Stability

1. In the bromination of n-butane, the secondary hydrogens are 20 times more reactive than the primary hydrogens. What is the product ratio of 1-bromobutane to 2-bromobutane? a. 6:4 b. 1:20 c.93:7 d. 7:93 2. Rank the free radicals (I-III) shown below in order of decreasing stability (ie, most stable to least s


1. An energy maximum in a reaction-energy diagram would be labeled as which of the following? a. Reactant b. Product c. Transition State d. Intermediate 2. Which of the following best describes the shape of the methyl free radical? a. linear b, planar c, tetrahedral d. pyramidal

5 Chemistry Problems on alkanes

1. Which of the following correctly lists the following isomeric alkanes in order of increasing boiling point? n-hexane, 2,3-dimethylbutane, 2-methylpentane a. n-hexane < 2-methylpentane < 2,3- dimethylbutane b. 2-methylpentane < 2,3-dimethylbutane < n-hexane c. 2,3-dimethylbutane < 2-methylpentane < n-hexane d. n-hexa