1) What do understand by the terms a) Empirical Formula b) isomerism and what conclusions can you draw from the following observations about the chemical nature of the organic liquid D? a) D (relative molecular mass 72 ) has the following persentage composition by mass: Carbon 66.7, hydrogen 11.1, oxygen 22.2 b) D gives an
1. A proton that absorbs radio frequency radiation at higher field strength will appear _____ in a 1H NMR spectrum. a. at 0 ppm b. downfield (away from TMS) c. upfield (closer to TMS) d. at 7.27 ppm just like CDCl3 2. The carbonyl peak of benzaldehyde appears as a very strong and intense peak at 1703 cm^-1. Normally the
A) Why is GC not able to distinguish between the trans vs. cis-2-pentene products? b) Explain why the 3-pentanol 13C-NMR spectrum contains three peaks while the trans and cis-2-pentene spectra contain five peaks (note that 13C-NMR gives a peak for each unique carbon, i.e. identical carbons show up as the same peak).
We are asked to explain the phenomena of how 1 gram of liquid water at 35 degrees C (as in a pond or lake) evaporating into an overlying air mass at a temp of 65 degrees C and a relative humidity of 50%. What actually causes the evaporation of water and how can this be calculated in this instance?? What is the vapor pressure
1. Draw structural diagrams and give the names for the isomers of pentane. 2. When 2-butene reacts with hydrogen chloride gas, only one product is detected, whereas when 1-butene reacts similarly, two products are usually found. Explain this. 3. Geometric isomers exist in the alkenes but not in the alkynes. Explain why.
In this problem the H NMR spectrum of styrene oxide shows that protons 1, 2, and 3 all have different chemical shift values. Proton 2 is coupled to both proton 1 (J= 5.8 Hz) and proton 3 (J=2.5 Hz). Draw a scale tree diagram and your best rendering of the resulting peaks for proton 2. See attached file for full problem desc
Are there differences between having electron-donating groups and electron-withdrawing groups on benzoate esters? Why or why not?
Giving reasons for your answers, indicate whether each of the following formulas is saturated, unsaturated, or impossible to exist. A. C2H5 B. C4H10 C. C3H12 D. C2H2 E. CH2
1) How many grams of CO2 can you obtain from the combustion of 280 g of butane? 2) Write the developed formula of the following compounds (they are in Spanish) a) 2Chlorine 2metil 1hexanol b) 3 hidroxipentanoico c) Etanoato de metilo d) Metal propel amina e) 3 hidroxi 1metil benceno 3) Assign the name and complete wi
Assign formal charges to each atom in the attached file. Cross out the configurations that are not reasonable, and provide an explanation (eg large charge, incomplete octet, octet exceeded).
Match a structure from the attachment to: a. an octapeptide with a C-terminal valine. b. an amino acid in its zqitterionic form. c. a polypeptide which gives four fragments on treatment with chymotrypsin d. the product of an edman degradation e. a carboxyl-protected amino acid. f. a peptide coupling reagent 36. sm
What is the correct structure for D-glucopyranose? What is the relationship between the following compounds? a) anomers b) meso compounds c) enantiomers d) equivalent structures What is the relationship between the following compounds ? a) anomers b) meso compounds c) enantiomers d) equivalent structures
What are the advantages of NMR and MS write one compound which you can identify using each of these techniques.
(See attached file for full problem description) p_Ethyl aniline is treated with NaNO3 in HCl to generate the diazonium salt. For the first two, show what reagents are necessary to convert the salt to the products shown below. For the third, show what product is obtained. Synthesize the following compounds using the startin
1. What are the ingredients of a cephalin? 2. Which fatty acid is always unsaturated in a cephalin? Why? 3. What is the enzyme system used in the formation of the prostalandins and thromboxanes? 4. Would you expect sodium ions (Na+) to be able to pass easily into a cell through bi-layer membrane wall? Why or Why not?
Third period elements react with O2 to form Al2O3, SiO2 and P2O5. What is formed with Germanium and Oxygen?
Please answer the following questions. 1. Using sketches, demonstrate why the addition of HCN to 2-butanone yields a racemic mixture of chiral products. Circle the chiral carbon in each product. 2. Describe spectroscopic or chemical tests to distinguish between the following pairs of compounds: a. 2-pentanone vs 2-pentano
Methanol, Ethanol, & 1-Propanol 1) How would you sketch these three alcohol molecules? 2) What is each of their polarity? 3) What differences might you expect in the comparative solubility of each of them in lipids? WHY??? 4) If you were to add 2 drops of sheep blood to each of these alcohols (about 1/3 of a small te
In the mass spectrum of butylbenzene, the base peak occurs at m/z a. 134 b. 119 c. 105 d. 91 The number of mono-bromination products of p-xylene is a. 1 b. 2 c. 3 d. 4 Which of the following compounds has the lowest boiling point? a. p-dichlorobenzene b. o-dichlorobenzene c. m-
I need some help with answering these questions: (See attached file for full problem description and structural formulas) 1. Predict whether the molecule would be expected to show aromatic character or not. Explain your answer. 2. What is the hybridization of the nitrogen atom in sulfathiazole? 3. Assuming that the sulfur
What are the structural formulas and names of all possible isomers for Methanol, 1-Propanol, & 1-Pentanol?
What are the possible isomers for Methanol, 1-Propanol, & 1-Pentanol? Are Methanol, 1-Propanol, & 1-Pentanol soluble in water and also in hexane? Why or why not? Why isn't it possible to make a ketone molecule out of a methanol or ethanol molecule? Is it because they have been oxidized?
How would you write the structural formula for trans-3,4-dimethyl-3-hexene?
Is it possible to identify what the hydrocarbon is with just knowing the volume of it (9.61 ml), the mass (7.669 g/ml), density (0.798 g/ml)? Under tensor lamp, in ambient light, and in dark light there was no color noticed. It smelled somewhat like gasoline maybe and was smoky as far as combustion characteristics. Boiling poin
Benzene is a organic solvent with the formula, CB6BHB6B. It boils at 80.1 C and melts at 5.5 C. Benzene's density is 0.88 gm/ml, its heat of vaporization is 20.0 KJoules per mole, its heat of fusion is 10.0 KJoules per mole, its heat capacity is 0.50 KJoules per mole-degree C for liquid benzene, 0.25 KJoules per mole-degree C fo
How many unpaired electrons are in nickel atom? Use electronegativity values to arrange the following bonds in order of increasing polarity. H---F H---CL C---S C---O
Determine how many valence electrons and if it is neutral 1s2, 2s2, 2p3 1s2, 2s2, 2p6 1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d6 AR 4s2, 3d5 Kr 5s2 4d10, 5p5
Some isomeric products were isolated from the free-radical chlorination of (R)-sec-butyl chloride. a) Draw stereochemical structures of the 1,2-, 2,2, and 1,3- dichlorobutanes obtained in this way. Give the proper R/S specification of 1,2 and the 1,3-dichlorobutanes. b) Which of these fractions as isolated will be optically act
A. trans-dichloroethene B. 2,4,4 trimethyl-2-pentene C. 2,4,4 trimethyl-1-pentene
89. A) We often hear the terms organic, natural, and chemical in the media. Organic and natural are usually used to imply that a product is "healthy" and/or "environmentally friendly" while chemical often implies negative implications for health and for the environment. In your opinion, are these implications justified? Us