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best method for the preparation of 3-chloro-3-ethylpentane

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Which one of the following represents the best method for the preparation of 3-chloro-3-ethylpentane?

a. (CH3CH2)3CH + Cl2 â?' (CH3CH2)3CCl + HCl
b. (CH3CH2)3CH + HCl â?' (CH3CH2)3CCl + H2
c. (CH3CH2)3CH + NaCl â?' (CH3CH2)3CCl + NaOH
d. (CH3CH2)3COH + HCl â?' (CH3CH2)3CCl + H2O
e. (CH3CH2)3COK + Cl2 â?' (CH3CH2)3CCl + KCl

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Best method for the preparation of 3-chloro-3-ethylpentane, correct option is given along with the suitable reasoning.

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