PROBLEM: Treatment of one stereoisomer of (2 ?, 3R)-2-iodo-3-phenylbutane with base, yields (E)-2-phenylbutene. a) Determine which enantiomer of 2-iodo-3-phenylbutene gives the E product (2R, 3R or 2S, 3R), and explain clearly (using unambiguous diagrams) why that is the case. b) Assign that enantiomer as either R or
Stereoisomers in organic chemistry. See attached file for full problem description.
Please see attached... I chose there are a total of 2 steroisomers and both are optically active
9. a. Using Fischer projections, draw all the possible stereoisomers 2, 4-dihydroxybutane (CH3-CHOH-CHOH-CH3) b. Label the relationships of your answers in "A" as enantiomers, diastereomers, or Meso ( if any) c. Assign absolute configurations to the chiral carbons n one of your Fischer projections. d. Indicate which of the
How many possible trisubstituted derivatives C6H3X2Y can be obtained from the para disubstituted benzene C6H4X2? (Ignore directie effects of the substituents X and assume that all positions on the ring are accessible to the reagent Y+).
Match the structures below with the best description of the type of alkyl halide... See attached Provide structures of products for the following reactions. Include 3-dimensional stereochemistry and absolute configurations where appropriate. If more than one product is possible, circle that which is predominant.
The chlorination of propane yields 4 different dichloropropanes of formula C3H6Cl2. Using the following information to identify dichloropropanes A,B,C,D. i. If each dichloropropane is further chlorinated to yield trichloropropanes. Compound A gave one trichloropropane, B gave two, C and D each gave three. ii. Dichloropropane D
Draw the enantiomer of cis-1-chloro-3-methylcyclopentane which is R at C-1. 1) What is the configuration of this molecule at C-3 (R and S)? 2) When cis-1-chloro-3-methylcyclopentane and trans-1-chloro-3-methylcyclopentane are treated with sodium iodide in aqueous acetone, their rates of substitution are strikingly differ
Draw a molecular structure formula formula for an acyclic alkane with eight carbon atoms.
"Draw the structure of the major organic product of each of the following four reactions (one in the first file, two in the second file). Indicate stereochemistry if appropriate." Please see the attached files.
Consider the bromination of the compound 2-methyl 1-pentene in the attached file. 1. write the basic structure of the product of the bromination of 2-methyl 1-pentene, without regard to stereochemistry. 2. Does the product have any chiral carbons? If so, identify them with an circle. 3. How many stereoisomers are for
How many different tetrapeptides containing 2 molecules of alanine and 2 molecules of valine could theoretically exist? What are they? Write in shorthand.
Draw the structure for: a) 4-methyl-2-chloro pentanal b) trans-3-chloro-2-fluoro cyclopentanone c) 3,5-dipropyl benzaldehyde d) 1,3 cycloheptadione
Before spectroscopy was invented... a) Draw the structures of these two isomers. b) A turn of the 20th century chemist isolated an aromatic compound... Please see attached for further explanations
On the attached pages are the combined IR, 1H NMR and 13C NMR for Problems 1 and 2. Systematically solve the structure for each one. Provide the structure in the space attached, also, fill in the information requested on the table attached. Thank you!
Please help to solve the attached chemistry problems.
I am trying to come up with a structure for a conjugated diene that would give the same product when HBr is added in either a 1,2-addition or in a 1,4-addition.
When 1-pentene reacts with N-bromosuccinimide, two products with the formula C5H9Br are obtained. What are these products and how are they formed?
Is carrageen digestible by humans and why?
Part I: Refer to attachment for stereochemistry. Part II: TEMP(C) mmHg TEMP(C) mmHg Benzene 30 120 Toluene 30 37 40 180 40 60 50 270 50 95 60 390
Please refer to attachments provided for the full problem descriptions.
Draw an example of a meso compound with the formula C9H20.
Please give me the major organic products of the attached reactions. Stereochemistry is needed.
Please identify the structure giving the following spectra (NMW, IR, Mass Spec, etc.) (attached) and state how you arrived at your structure (give reasons such as peak identifcation and mass, etc.).
I attempted some of this but I am clueless as to some of the other stuff. Can you help? 2) Why are the products attached to C3 of 1,4 pentadiene more acidic than the methyl hydrogen atoms of propene? Maybe you can help me with this one. Are the C3 atoms more acidic because there is more s character involved with the ato
What is the absolute stereochemistry of the asymmetric carbon in compound O? When compound O is treated with lithium diisopropyl amide, followed by allyl bromide, compound P is produced as a single stereoisomer. What is the absolute stereochemistry of the newly produced asymmetric carbon in P? Provide concise explanations for
Draw the possible chair forms of cis and trans 1-isopropyl-3-methylcyclohexane. Are the two forms identical, enantiomeric, or diastereomeric? In each case, indicate which chair term will be more stable and explain why. Is either of these molecules chiral?
Draw the structure of the major organic product for each of the reactions shown below. If you can show stereochemistry, where relevant will help me out. Please see the attached file for full problem description.
I have tried to work out the following problem. Attached to this is a file that show NMR, IR and Mass spec info. I have come up with what I think the compound is but it does not work because the formula has more than one o. I have circled the carbonyl peak as well as the sp3 C-H peak.
Suggest structure fragmentation patterns that account for the following observed peaks in the mass spectra. A) 5-methyl-2-hexanone, m/e= 71, 58, 43 B) C6H5CH2OCH3, m/e= 122, 121, 91, 77 C) 1-bromopropane, m/e= 124,122, 43, 29, 15