QUESTION 1 Imagine that you are in chemistry lab and need to make 1.00L of a solution with a pH of 2.50. You have in front of you: - 100mL of 7.00x10-2 M HCl - 100mL of 5.00x10-2 M NaOH, and - Plenty of distilled water. You start to add HCl to a beaker of water when someone asks you a question. When you return t
To do this assignment, use your calculator to do the calculations required. Then invert the calculator to read the message word. Insert the message word into the appropriate space in the statement. Round off all atomic masses to the nearest whole number before using them. When handing in your assignment, be sure to show all
At low to moderate pressures, the equilibrium state of the water gas shift CO (g) + H2O (g) CO2 (g) + H2 (g) reaction is approximately described by the relation kp = (see attached file) The feed to a continuous shift reactor contains 30 mol% CO, 10 mol% CO2, 40 mol% water and the balance an inert gas. Th
The purpose of lab this week is to do "comfirmatory experiments" that further explore the properties of your unknown compound and confirm that it reacts appropriately for the compound you predicted it to be at the end of lab last week. 1. Suppose your unknown is sodium acetate. When a solution of calcium chloride is adde
Please help with the following physical chemistry problem: Alcoholic fermentation by microorganisms involves the breakdown of glucose into ethanol and carbon dioxide. C6H12O6 (s) -->; 2 C2H5OH (l) + 2 CO2 (g) a) Calculate the amount of heat liberated in a yeast brew upon fermentation of 1 mol of glucose at 25 °C and 1
Part A. Standardization of the 0.02 M KMnO4 solution with Fe(NH4)2(SO4)2 ? 6H2O. (Molecular weight of the ferrous sulfate hexahydrate is 392.16 g/mol). If you weigh out 1.01 g of the Fe(NH4)2(SO4)2 ? 6H2O, how many moles of iron (Fe+2) are in the sample? Part B Assume you fill a buret with your KMnO4 solution and the v
In this introduction are given the explanation of how to find out an empirical formula if one has found out the chemical elements of an unknown substance and measured their ratio of masses. Also, it is described how one can calculate the ratio of masses from a given empirical formula. Two examples and the explanation of the pri
Please help with the following problem. Provide step by step calculations in this answer. A 25.00 mL sample containing Cu2+ gave an instrument signal of 23.6 units (corrected for a blank). When exactly 0.500 mL of 0.0287 M Cu(NO3)2 was added to this solution, the signal increased to 37.9 units. Calculate the molar concentrat
The molar heat capacity of C6H6(l) is 136 J/mol x degrees centigrade and of C6H6 (g) is 81.6 J/mol x degrees centigrade. The molar heat of fusion for benzene is 9.92 kJ/mol and its molar heat of vaporization is 30.8 kJ/mole. The melting point of benzene is 5.5 degrees centigrade, its boiling point is 80.1 degrees centigrade and
Determine the strength of 5 antacids via addition to a known amount of acid, followed by titration with base. Determine which is most effective per dose and per gram.
Imagine yourself as the Lead Analytical Chemist at Kaplan Industries. Your first big assignment is to investigate the strength of several commercial antacids for the Food and Drug Administration (FDA). They have sent five antacids to be tested with a back-titration that works as follows: ? First, each antacid tablet is mixed w
1.Given the molar concentration of hydrogen ion [H+] = 6.2 x 10 -7, calculate the concentration of hydroxide ion. 2.Given the molar concentration of hydroxide ion [OH -] = 4.6 X 10 -13, calculate the concentration of hydrogen ion. 3. In 1 mL of water there are 3 X 1022 molecules of H2O. How many hydrogen ions are in 1 mL o
16. A compound contains 40.00% carbon, 6.67% hydrogen, and 53.33% oxygen. Determine the empirical formula of the compound. Please help with the following problems. 1. Give the chemical formula for calcium phosphate. 2. A hypothetical element, Js, has three naturally occurring isotopes. The atomic mass and relative abunda
What is the pressure in atmospheres of 201 grams of O2 gas in a 12.0 liter vessel at 25.0OC?
4.) Determine the concentrations of hydronium and hydroxide ions in 0.0403 M aqueous sodium hydroxide. Kw = 1.0E-14. A.) Hydronium ion concentration?(answer in M) B.) Hydroxide ion concentration?(answer in M) 6.) Concentrated aqueous HClO4 has a concentration of 14.8 M. Calculate the concentrations of all ions present in a
A sample of nitrogen gas has a volume of 3.00 L at 25 degrees C. What volume will it occupy at each of the following temperatures if the pressure and number of moles are constant: a) 546K b) 273K c) 373K
A 0.213-g sample of uranyl(VI)nitrate, UO2(NO3)2, is dissolved in 20.0 mL of 1.0 M H2SO4 and shaken with Zn. The zinc reduces the uranyl ion, UO2 (with a charge of 2+), to a uranium ion, Un+ (where n+ is the charge of the uranium ion). To determine the value of n, this solution is titrated with KMnO4. Permanganate is reduced to
1) How many milliliters of 0.480M NaOH would be required to titrate a 5.00ml solution of 0.320M H2SO4? Report answer to the correct number of significant figures. 2) Write a balanced equation for the combustion of octane, C8H18. 3) If the standard enthalpy of formation (deltaHf) of methanol, CH3OH, is -238.6kJ/mol, deltaHf(CO
Explain qualitatively how the following would change the calculated surface concentration of SO2 assuming a gaussian plume from a smoke stack that follows the gaussian equation for the concentration of SO2 i) The wind speed decreased. ii) The wind speed increased. iii) A stable temperature profile became unstable. iv) An
Write the reactions responsible for the LIQUID PHASE oxidation of S(IV) to S(VI), and show how the oxidation can lead to a decrease in pH of rain water. I think you can help me with this. Please let me know. I've included all details.Thank you Dr. M. There are two sets of reactions with 3 parts for each set. I'm not sure w
Some backround data: mass of NiCl2 + 6H2O = 3g mass of Ethylenediamine used: 2.85g initial moles ethylenediamine: .0474 (I think) product formed: mass of Ni(C_2_H_8_N_2_)_3_CL_2_: 3.597 The questions I need answered: -theoretical moles of product, based on stoichiometry. -molecular mass of product -theoretical mass o
Diagram and explain the H-Bonds if they exist for the following molecules: (a.)H2S, (b.)CH4, (c.)H2SO3, and (d) PH3. Give reasons for the fact that ionic solids as NaCl have high melting points and dissolve readily in water, whereas network solids such as diamond have very high melting points and do not dissolve in water.
1. Combustion of 2.016 grams of solid sucrose (C6H12O6) at 25 º C in a bomb calorimeter with heat capacity 9550 J K -1 gives a temperature rise of 3.282 º C. a) Write the balanced equation for the combustion of sucrose b) What is the work done by the system? c) What is the heat change per mole of sucrose for the reaction?
Suggest the pressure and temperature at which 1.0 mol of (a) Nh3, (b) Xe, (c) He will be in states that correspond to 1.0 mol of H2 at 1.0 atm and 25 degrees Celsius. NH3: T = 3.64 x 10^3 K, p= 8.7 atm, Xe: T=2.60K, p=4.5 atm, He: T=46.7K, p=0.18 atm.
Please see attached file. A scientist proposted the following equation of state P = RT/Vm -B/Vm^2 + C/Vm^3 where B and C are independent of the temperatures. Show that the equation leads to critical behavior. Find the critical constants of the gas in terms of B and C and expression for the critical compression factor
If you add Na2CO3 with NaHCO3 and distilled water what is the equilibrium expression for the buffer? And what is the weak buffer and the conjugate base? What Ions are present in the solution?
1. The pressure on each of the following systems is decreased from 5 atm to 1 atm. Which way does the equilibrium shift in each of the following systems? a.) 2CO2 (g) --> 2CO (g) + O2 (g) b.) H2 (g) + I2 --> 2HI (g) 2. What is the pH of a solution if the H+ concentration is 7.2 X 10^-14 M? Is this neutral, acidic, or ba
You add 5 drops of .100 M HCl to 100ml of "pure" water. Assuming that the volume of one drop is .035ml, calculate the expected pH of the resulting solution. .
1. In earlier times, ethyl ether was commonly used as an anesthetic. It is, however, highly flammable. When 5.0 mL of ethyl ether C4H10 (l), (d=0.714 g/mL) is burned in a bomb calorimeter, the temperature rises from 23.5°C to 39.7. The calorimeter heat capacity is 10.24 kJ/°C. What is heat released when 5.00 mL ethyl ether is
GIVEN INFO: from an unknown bottle: Unknown= #25 Metal present= Na Mass% metal= 43.88% Atomic masses: Cl= 35.453g O= 16.0g C= 12.0g H= 1.00g 1. Mass of crucible and cover= 32.493g 2. Mass of crucible, cover, and unknown=33.001g 3. Mass of crucible, cover, and solid chloride= 33.017g -----------------------------
1. Some sulfuric acid is spilled on a lab bench. It can be neutralized by sprinkling sodium bicarbonate on it and then mopping up the resultant solution. The sodium bicarbonate reacts with sulfuric acid as follows. 2 NaHCO3(s) + H2SO4(aq) Na2SO4(aq) + 2 H2O(l) + 2 CO2(g) Sodium bicarbonate is added until the fizzing due to th