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Energetics and Thermodynamics

Extent of reaction as function of temperature

If given the change in entropy and the change in enthalpy, derive an expression for the extent of the reaction as a function of temperature. Please look at the attached diagram for an adequate description.

Determining the Efficiency of a Water Heater

Some of the butane, C4H10(g), in a 200.0 liter cylinder at 25.0 degrees C is withdrawn and burned at a constant pressure in an excess of air. As a result the pressure of the gas in the cylinder falls from 2.35 atm to 1.10 atm. The liberated heat is used to raise the temperature of 132.5 liters of water from 25.0 to 62.2 degree

Carbon Monoxide and Hydrogen Reaction

Consider the reaction CO(g) + 2 H2(g) <-> CH3)H(l) at 25 degree C. Change Gdegree(CO) =-137.3 KJ/mol change Gdegree (CH3OH)= 166.3 KJ/mol change in Hdegree (CO) = -110.5 KJ/mol change in Hdegree (CH3OH) = 238.7 KJ/mol Sdegree (CO) = 197.9 J/K x mol Sdegree (CH3OH)= 126.8 J/K x mol Calculate Sdegree(H2(g)) Show

Decomposition of Nitrosyl Chloride

Nitrosyl chloride (NOCl) decomposes at elevated temperatures according to the eqation 2 NOCl(g) <-> 2 NO(g) + Cl2(g) Calculate Kp for this reaction at 227 degrees C. For this reaction change in Hdegree =81.2 KJ/mol, change in Sdegree= 128 J/K x mol

Calculating Heat of Combustion

The DH of combustion of CH4 is -882kJ/mol.How many grams of water, which has a specific heat of 4.184 J/g-oC can be heated from 30oC to 95oC by the heat produced in the combustion of 2.25 mol of CH4?

Spontaneous Reactions and Entropy

Consider the reaction : 2H2(g) + O2(g) ---> 2H2O(l). In this reaction, matter is less dispersed, leading to a decrease in entropy since the reactants are gases and the product is liquid. Nevertheless, the reaction is spontaneous. Explain why this is so.

Inorganic Thermodynamics: Corresponding Reactions

Note: &#61508; stands in for other symbols. PLEASE SEE ATTACHMENT FOR PROPER FORMULA SYMBOLS. Given the following data: &#61508;G&#61616;f Ca2+(aq) = -553 kJ / mol &#61508;G&#61616;f Cl-(aq) = -131 kJ / mol &#61508;G&#61616;f CaCl2(s) = - 748 kJ / mol &#61508;G&#61616;hyd Ca2+(g) = -1517 kJ / mol &#61508;G&#61616;hy

Inorganic Thermodynamics

Aluminum oxide (Al2O3) is a widely used industrial abrasive (corundum, emery), with its specific application depending on the hardness of the crystal a) How is the hardness of an ionic material related to its lattice energy? b) Knowing the relationships between lattice energy and: 1) charges and 2) atomic radii, would you

Inorganic Thermodynamics: Enthalpy Change

Question: For water, (delta) Hfus = + 6.01 kJ/mol and (delta) Hvap = +40.67 kJ/mol. What is the enthalpy change associated with the deposition of 1.24 mol of water vapor?

Inorganic Thermodynamics

Calculate the standard enthalpy of formation of gaseous diborane, B2H6, using the following thermochemical information: (See attachment for full question)

Inorganic Chemistry Midterm Study Guide

Please do all of the midterm. These are the sections that will be covered in our midterm please complete with long explanations as well as giving related info to questions asked. Thanks.

Heat Loss and Specific Heat

a) A student wishes to determine the specific heat of a metal using a coffee cup calorimeter (calorimeter constant 50.35 cal/degrees Celsius). The student heats 130.56 grams of unknown metal from 25.0 degrees Celsius to 100.4 degrees Celsius. The initial temperature of the calorimeter (coffee cup plus 30 mL water) was 23.5 degre

Work of expansion

One mole of nitrogen gas confined within a cylinder by a piston is heated from 9.1°C to 883.6°C at 1.30 atm. Calculate the work of expansion (include sign) in joules (1 J = 9.87à?10-3 atm L). Assume all of the energy is used to do work.

Reaction equations and mass

Please give step by step solutions and answers. 1) Write the balanced molecular equation for the reaction of calcium with molecular oxygen to form calcium oxide. 2) You start out with an empty crucible weighing 19.3350g. After adding some calcium to the crucible, the mass is now 22.1156g. After heating the calcium and co

Combustion & Mass

Limestone(CaCO3) is used to remove acidic pollutants from smokestack flue gases in a sequence of decomposition-combination reactions. The limestone is heated to form lime (CaO), which reacts with sulfur dioxide to form calcium sulfite. Assuming a 74.7% yield in the overall reaction, what mass of limestone is required to remove a

Chemistry review questions

Question 2 An imaginary element X consists of two isotopes having masses of 110.00 amu and 112.00 amu. ("amu" is an atomic mass unit.) A sample of X was found to consist of 79.94% 110X and the rest is 112X. What would be the average atomic mass of X in this sample? Give your answer to four significant figures. Do not enter a

Evaluting Melting Point Determination

1. In a mixture of approximately 20% camphor and 80% naphthalene. What would you expect the melting point to be? (+/-)camphor (175-177 Celsius) and naphthalene (80-81 Celsius). 2. Describe the expected type of error in the observed m.p. (unaffected, high, low and/or broad) when the melting point is determined as follows: a.

Entropy of mixing

I am trying to figure out how, for the entropy of mixing of two polymers, one gets from: Change in entropy of mixing (delta S sub m) = k[(N1 + N2) ln (N1 + N2) - N1 ln N1 - N2 ln N2] to the result: change in entropy of mixing (delta S sub m) = -k(N1 ln v1 + N2 ln v2) where v1 and v2 are the volume fractions of the two

What is the percent of CdSO4 by mass in a 1.0 molal aqueous solution?

1. What is the percent of CdSO4 by mass in a 1.0 molal aqueous solution? 2. Calculate the amount of heat that must be absorbed by 10.0 gram of ice at -20 C to convert it to gaseous water at 110 C. Given: Specific heat ice = 2.1 Joule/gram water = 4.184 Joule/gram steam = 1.84 Joule/

Molar enthalpy of vaporization

The normal boiling point of bromine is 58.8 C. Given that the vapor pressure pressure of methanol (sic) is 75.0 torr at 2.5 C, Calculate the molar enthalpy of vaporization of bromine. Show all work and thanks for your help and time.

Melting and Vaporizing

Show the heating curve of a subtance that melts and then vaporizes. (a) Sketch the heating curve of carbon dioxide at atmospheric pressure, starting at -100 C and ending at 30 C. (b) Sketch the same heating curve as it would appear at a pressure of 10 atm. (c) Under what conditions would the heating curve resemble the on

Colligative Properties - Boiling Point and Freezing Point of Water

Show how the boiling point and freezing point of water are affected by the addition of various solutes. (a) If you were to dissolve 10 g sodium chloride in 500 g water, what would be the boiling point of the solution? (b) If you were to heat the solution in part (a), and continue heating it as it boiled, what would happen to th

Enthalpy Of Solution

Look at the dissolution of various salts. Compare the dissolution of sodium hydroxide with that of sodium chloride. a) How do the energy changes for the overall processes compare? b) Discuss the difference in magnitude of each of the three steps for dissolution of the two compounds.

Heat of formation

Methylene chloride can be prepared from the reaction of methane and chlorine, by the following equation: CH4(g) + Cl2(g) ---> CH2Cl2(g) + HCl(g) Calculate the standard heat of formation in kilojoules for the reaction using the following measured heats of formation. HCl(g) + CH3Cl(g) --> CH4(g) + Cl2(g) Delta H = +98.3 kJ CH

Entropy Change

Question: The reaction of ammonium nitrate when added to water is endothermic (H=25.7 kJ) and can be written as: NH4NO3(s) + H2(l) ---> NH4NO3(aq) a) Determine the heat of formation of NH4HO3(aq). b) What would be the final temperature of a solution that contained 50 grams of NH4NO3 dissolved in 125 mL of water. Use a spec