The chlorination of propane yields 4 different dichloropropanes of formula C3H6Cl2. Using the following information to identify dichloropropanes A,B,C,D.
i. If each dichloropropane is further chlorinated to yield trichloropropanes. Compound A gave one trichloropropane, B gave two, C and D each gave three.
ii. Dichloropropane D has a chiral carbon.
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If you sit down to draw out the four possible dichloropropanes, you will find out that they are:
Assume that all the methylene groups in the alkane are equally reactive as sites of free-radical chlorination.
a) Photochemical chlorination of heptane gave a mixture of monochlorides containing 15% 1-chloroheptane. What other monochlorides are present? Estimate the percentage of each of these additioanl C7H15Cl isomers in
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1. Which reaction sequence would be best to prepare m-chloroaniline from benzene?
a. chlorination, nitration, reduction
b. nitration, reduction, chlorination
c. nitration, chlorination
d. nitration, chlorination, reduction
e. nitration, reduction, acet
Explore the following statement: "The answer to a waterborne disease outbreak is to 'shock' chlorinate." What health risks would be mitigated with this approach? What new health risks might emerge from the application of large doses of chlorine?
1. Write a detailed, stepwise mechanism to account for the following reaction. Be sure to include ALL the components of the mechanism.
hr
CH3CH2CH3 + BR2 -> CH3CHBrCH3 + HBr
2. When 2, 2-dimethylbutane is subjected to free radical chlorination, the relative reactivity of the types of hy
Draw electron-dot formulas for the following ionic species. Show the formal charges on individual atoms in each ion.
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Organicchemistry structural problem with for Methyl Ketone:
In organicchemistry, there is a ketone structure that has the carbon bonded twice with the oxygen(C=O)with two components on the side...the question is how or where do I attach the methyl(CH3) on to this Ketone structure? (See attachment for diagram)
4. For the reactions:
Cl + H-CH3 --> Cl-CH3 + H
Cl + H-CH3 --> CH3 + H-Cl
a) Calculate the change in H for each reaction using bonds dissociation enthalpies.
b) One of these reactions is the rate-determining step in the correct mechanism for the chlorination of methane. What is it? Explain why, based on
