Explore BrainMass
Share

Explore BrainMass

    Monochlorination Products of this Reaction

    This content was COPIED from BrainMass.com - View the original, and get the already-completed solution here!

    Organic Chemisty 1 CHEM 307.002
    Exam 7 Review (50 points maximum)

    1. Please complete the following reactions by supplying the missing reactants or product(s) as indicated by a ? mark. Do not balance and do not show inorganic products or mechanisms. (22 points.)

    2. Consider the reaction below to answer the following questions. (8 pts.)

    a. Draw all the monochlorination products of this reaction.[Hint: there are four products]

    b. Place a circle on the monochlorinated product(s) that have chiral carbon(s).

    c. Briefly explain whether this radical chlorination is an oxidation or reduction process.

    3. draw structures corresponding to the following names. Show proper number of hydrogens (condensed form, such as CH3 is fine) about each carbon atom except for cyclic structures that may be shown in polygons. (10 pts.)

    (1) (E)-2,3-dibromo-2-butene (2) (S)-2-aminopropanoic acid

    (3) (2R, 3S)-dibromobutane (Fischer Projection ) (4) 5-ethyl-3,4-dimethyloctane

    (5) Determine whether the chiral carbon in the following structure is the R- or S-configuration. Show how priorities are determined.

    4. A hydrocarbon A, which is optically active, has the formula C7H12. It absorbs two equivalents of hydrogen H2, gas on catalytic reduction over a palladium catalyst to give an optically active hydrocarbon B with formula C7H16. On partial hydrogenation with one equivalent of H2 gas, it gives optically active (Z)-4-methyl-2-hexene. Upon ozonolysis, of hydrocarbon A, only two products are formed: acetic acid (CH3CO2H), and (R)-2-mehtylbutanoic acid. Propose structures for compound A and B. (10 points).

    © BrainMass Inc. brainmass.com October 10, 2019, 12:16 am ad1c9bdddf
    https://brainmass.com/chemistry/acid-and-base-organic-chemistry/monochlorination-products-reaction-285337

    Attachments

    Solution Summary

    The expert examines monochlorination products of the reaction.

    $2.19