(a) Based on this mechanism, derive an expression for the velocity (rate) of the reaction of the concentration of only reactants and stable product.
(b) In a particular ecperiment, equal concentrations of A and B are mixed together, and both the inital rate vo and the half-life t 1/2 are determined. Based on your answer to part (a), predict for a subsequent experiment:
(i) The effect on vo if the initial concentrations of both A and B are doubled.
(ii) The effect on t 1/2 if the initial concentrations of both A and B are doubled.
(iii) The effect on vo if the initial concentration of A id unchanged and the initial concentration of B is increased tenfold.
Solution Preview
The whole reaction can be written as:
2A + A + B <-> A2 + C -> P + 2A
or, 3A + B <-> (A2C) -> P + 2A
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