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Spectroscopic Method

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What spectroscopic method is best for distinguishing between isomeric compounds? Could you please give an example of how each of these would be interpreted.

Valeric acid CH3(CH2)3COOH
3-methylbutanoic acid (CH3)2CHCH2COOH
Pivalic acid (CH3)3CCOOH.

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The solution determines what spectroscopic method is best for distinguishing between isomeric compounds.

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