# Electrochemistry Problems

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Last minute cram for finals tonight. I found these as pertains to my weak areas, so, just to see if I am doing ok, if I am wrong, please correct me-I can probably find where I went wrong!

1. What mass of solid CaO is needed to remove the sulfur dioxide from 1.0 x 106 m3 of air having an SO2 concentration of 1.5 x 10-9 M? Assume that the reaction leading to removal of the sulfur dioxide is CaO(s) + SO2(g) CaCO3(s).

56 g

96 g

37 g

84 g

2. Calculate the equilibrium constant for the decomposition of water, 2H2O(l) 2H2(g) + O2(g) at 25oC, given that G (H2O(l)) = -237.2 kJ/mol.

0.83

6.3 × 10-84

2.5 × 10-24

1.6 × 1083

3. The equilibrium constant at 427oC for the reaction N2(g) + 3H2(g) 2NH3(g) is

Kp = 9.4 × 10-5. Calculate the value of Go for the reaction under these conditions.

-33 kJ/mol

-54 kJ/mol

54 kJ/mol

33 J/mol

4. Complete and balance the following redox equation that occurs in acidic solution using the set of smallest whole-number coefficients. What is the sum of all the coefficients in the equation?

PbO2(s) + Cl-→ Pb2+ + Cl2(g) (acidic solution)

(No choices give on this one) 5

5. Complete and balance the following redox equation using the set of smallest whole-numbers coefficients. What is the sum of the coefficients?

HI + HNO3→ I2 + NO (acidic solution)

5

7

14

17

6. Complete and balance the following redox equation.

Br2→ BrO3- + Br- (basic solution)

The sum of the smallest whole-number coefficients is

9.

12.

18.

21.

7. Complete and balance the following redox equation using the set of smallest whole-number coefficients. Now sum the coefficients of all species in the balanced equation. (Remember the coefficients that are equal to one.)

BrO3-(aq) + Sb3+(aq) → Br-(aq) + Sb5+(aq) (acidic solution)

4.

12.

13.

17.

8.If the measured voltage of the cell Zn(s) | Zn2+(aq) || Ag+(aq) | Ag(s) is 1.37 V when the concentration of Zn2+ ion is 0.010 M, what is the Ag+ ion concentration?

2.5 M

4.0 × 10-9M

6.2 × 10-3M

6.2 × 10-5M

9.Calculate the cell emf for the following reaction at 25oC:

Ni(s) + 2Cu2+(0.010 M) → Ni2+(0.0010 M) + 2Cu+(1.0 M)

0.40 V

-0.43 V

0.43 V

0.37 V

10. A current of 0.80 A was applied to an electrolytic cell containing molten CdCl2 for 2.5 hours. Calculate the mass of cadmium metal deposited.

3.2 × 10-7 g

1.2 × 10-3 g

4.2 g

8.4 g

#### Solution Summary

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