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Order of reactivity

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Suggest an explanation for the fact that the order of reactivity of the halides
toward n-butylbrosylate in acetone is Clֿ > Brֿ > Iֿ when (C4H9)4N+ is the cation of the halide
salt, but Iֿ > Brֿ > Clֿ when Li+ is the cation.

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Solution Summary

The order of reactivity are determined.

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The change in reactivity can be explained with the strength of the cation-halide interaction.
Li+ is very small. Its binding energy towards halide anions increases with decreasing ...

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