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Predicting reactivity and frequency in Carbonyl and Cyclopentadiene Complexes

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I have attached two questions which have me totally confused. Questions similar to these will be on my next test and I need to learn how to do them. Please include work and explanation. Thanks.

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Solution Summary

Rational approach for predicting relative reaction rates, reaction products and CO stretching frequency for various ligand substitution and nucleophilic addition reaction of carbonyl and cyclopentadiene complexes.