1. A 4 L sample of a diatomic gas with specific heat ratio 1.4, confined to a cylinder, is carried through a closed cycle. The gas is initially at 1 atm and 300 K. First, its pressure is tripled under constant volume. Then, it expands adiabatically to its original pressure. Finally, the gas is compressed isobarically to its original volume. Draw a P-V diagram of this cycle. Find the temperature of the gas at the start of the adiabatic expansion. Determine the volume of the gas at the end of the adiabatic expansion. Find the temperature at the end of the cycle. What is the net work done on the gas for this cycle?

2. One mole of H2 gas is contained in the left-hand side of the container, which has equal volumes left and right. The right-hand side is evacuated. When the valve is opened, gas streams into the right-hand side. What is final entropy change of the gas? Does the temperature of the gas change?

3. A 1.5 kg iron horseshoe initially at 600ºC is dropped into a bucket containing 20 kg of water at 25ºC. What is the final temperature if 100 g of water boils away? Ignore the specific heat of the container. (Specific heat of iron is 0.107 Cal/g*C. Latent heat of water vaporization is 540 cal/g)

4. Calculate the change in entropy of 250 g of water heated slowly from 20ºC to 80ºC.

Solution Summary

Answers to questions on work done on gas, entropy changes, temperature.

... a factor the pressure is for an ideal gas and then ... A reversible process changes the state of a system in ...Entropy of Reversible Process Entropy is defined for a ...

... result as in a) for the entropy because temperature... In case of the van der Waals gas the temperature... internal energy change in terms of changes in temperature...

... heat has to be transferred into the system to keep temp constant-- (presumably ... Energy gas is same. What I need now is entropy change & is it reversible. ...

...Changes in the system include internal energy, entropy, temperature, etc ... law (PV=nRT), the only way to increase the pressure in a gas without changing...

... does not stay in thermal equilibrium when it changes from state ... general formula of the entropy of an ideal gas as a ... by N k T Log(2). The entropy change of the ...

... values of entropy at the four states but only the changes in the ...Change in Entropy is defined as : dS = dQ/T. ... Also we know that the work done by the gas in an ...

...temperature is constant, one can write: ( 5) where is the entropy change caused by the heat change with the surroundings. Hence, the final volume of the gas...

... these, determine the temperature, 'pressure', and chemical potential of this gas. ... the temperature can be expressed as rate of change of entropy with respect ...

... d. What is the free energy change for boiling ammonia at 0C? ... S 28.9 ∆vap S 97.4 Cp (lq) 80.8 Cp(gas) 35.0 Note ... Standard entropy of fusion is given as (see Ref ...