Chemistry: Compounds in Equilibrium
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Compounds A and B are in equilibrium. For the reaction A --> B, E_s is 15 kcal/mol (62.8 kj/mol) and delta H in degrees is 12 kcal/mol (50.2 kj/mol). Draw a reaction profile diagram for this equilibrium. What are the E_s and delta H in degrees values for the reaction B --> A? What are the percentages of A and B in the reaction mixture at 25 degrees Celsius (assuming delta G = delta H approximately)? (See attachment for illustrations.)
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Solution Summary
The expert examines compounds in equilibrium. Reaction profiles are drawn.
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a. Stability of compounds is 1 > 3 > 2. This is because tertiary radicals are more stable than secondary than primary.
b. Stability of compounds is 3 > 1 > 2. This is because tertiary radicals are more ...
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