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Concentration, Saturation and Vapor Loss of a Gas in Tank

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Hello:

We are to assume a 129 m3 closed tank.

The tank previously contained heptane and therefore has residual vapor.

The vapor pressure is given and known as 40 mm Hg

The temperature is given as 25 degrees C.

1) Is there a way to determine what the residual concentration of heptane gas would be in this closed container?

2) Would you assume that the total enclosed container space was 100% saturated with heptane?

3) If a hole was drilled in the top of the tank, how would one calculate the vapor loss at stated pressure and temp?

Thank you so much.

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Solution Summary

This solution deduces the answers to a 3-part numerical problem, in a step-wise manner, with special attention to units and formula related to gas behavior.

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Answer to 510011

Q. How to determine the emission loss from a tank with a known gas or liquid
Hello:

We are to assume a 129 m3 closed tank.

The tank previously contained heptane and therefore has residual vapor.

The vapor pressure is given and known as 40 mm Hg

The temperature is given as 25 degrees C.

1) Is there a way to determine what the residual concentration of heptane gas would be in this closed container?

2) Would you assume that the total enclosed container space was 100% saturated with heptane?

3) If a hole was drilled in the top of the tank, how would one calculate the vapor loss at stated pressure and temp?

Thank you so ...

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  • "Thankyou for the feedback. I have a few question though; With the first statistic about cost below... “According to Sigma-Aldrich catalog, cost of 1L octane is AUD $ 392.00, whereas the cost of 1L ethanol is AUD $196.00. Moreover, if ethanol is obtained from sugar industry as a by-product, it may cost even less. Source of oxygen is ambient atmosphere, so it costs nothing. So ethanol is much cheaper than petrol, in fact it is half-priced: AUD $ (392-196) = $ 196.” I didn't think it made sense because the cost of petrol per litre is normally a dollar something or even less than a dollar not a couple of hundred of dollars. For example, a statistic that I found in america was: "U.S. ethanol production costs are about $1.20 per gallon of ethanol, or $1.82 per gallon on a gasoline-equivalent basis." However, I was wondering whether you could find an Australian statistic. Also, you mentioned that H20 is not a greenhouse gas. However, in the combustion equations it is actually carbon dioxide and water vapour which are produced and they are both greenhouse gases. Finally, how do I calculate the energy efficiency of ethanol and petrol? "
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