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Stoichiometry problem

In a location in Florida, water seeping into the ground contains 50 times as much carbon dioxide as rainwater. This ground water passes through a limestone deposit and ultimately into an underground spring. The spring has a flow rate of 2500 liters per second. How much limestone (CaCO3) in metric tons will be dissolved in this system in 1000 years?

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The solution is attached below in two files. the files are identical in content, only differ in format. The first is in MS Word XP ...