Chemical and Biochemical Engineering Homework Solutions
Problem
#5990

Half Life method

Problem:
The thermal decomposition of nitrous oxide (N2O) in the gas phase at 1030oK is studied in a constant volume vessel at various initial pressures of N2O. The half-life data so obtained are as follows:

po (mm Hg) 52.5 139 290 360

t1/2 (sec) 860 470 255 212

2N2O  2N2 + O2
Determine the rate equation that fits the data

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Problem1 CRE2.doc
Problem:

The thermal decomposition of nitrous oxide (N2O) in the gas phase at
1030oK is studied in a constant volume vessel at various initial
pressures of N2O. The half-life data so obtained are as follows:

po (mm Hg) 52.5 139 290 360

t1/2 (sec) 860 470 255 212

 2N2 + O2

Determine the rate equation that fits the data
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